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Selective Hydrogen Atom Abstraction via Induced Bond Polarization: The Direct α-Arylation of Alcohols via Photoredox, HAT and Nickel Catalysis
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation protocol for the selective functionalization of alcohol α-hydroxy C–H bonds. This approach employs zinc-mediated alcohol deprotonation...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6448405/ https://ncbi.nlm.nih.gov/pubmed/29490112 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201800749 |
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