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Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones via the Decarboxylative Arylation of α-Oxo Acids

The direct decarboxylative arylation of α-oxo acids has been achieved via synergistic visible light-mediated photoredox and nickel catalyses. This method offers rapid entry to aryl and alkyl ketone architectures from simple α-oxo acid precursors via an acyl radical intermediate. Significant substrat...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Chu, Lingling, Lipshultz, Jeffrey M., MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado: 2015
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4526169/
https://ncbi.nlm.nih.gov/pubmed/26014029
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501908
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