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Harnessing Alkyl Pyridinium Salts as Electrophiles in Deaminative Alkyl-Alkyl Cross-Couplings

A Negishi cross-coupling of alkyl pyridinium salts and alkylzinc halides has been developed. This is the first example of alkyl–alkyl bond formation via cross-coupling of an alkyl amine derivative with an unactivated alkyl group, and allows both primary and secondary alkyl pyridinium salts to react...

詳細記述

保存先:
書誌詳細
出版年:J Am Chem Soc
主要な著者: Plunkett, Shane, Basch, Corey H., Santana, Samantha O., Watson, Mary P.
フォーマット: Artigo
言語:Inglês
出版事項: 2019
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6434706/
https://ncbi.nlm.nih.gov/pubmed/30682254
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b00111
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