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Gold-Catalyzed Vinyl Ether Hydroalkynylation: An Alternative Pathway for the Gold-Catalyzed Intermolecular Reaction of Alkenes and Alkynes

In this report, the gold-catalyzed intermolecular reaction of vinyl ethers and terminal alkynes is investigated. Utilizing a triazole gold catalyst lessens gold decomposition in the presence of the vinyl ether and affords an alkynylation product instead of the [2 + 2] product. This protocol has been...

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Publicado en:Org Lett
Main Authors: Hosseyni, Seyedmorteza, Smith, Courtney A., Shi, Xiaodong
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6430632/
https://ncbi.nlm.nih.gov/pubmed/27978688
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b03228
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