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Accessing Alternative Reaction Pathways of the Intermolecular Condensation between Homo-Propargyl Alcohols and Terminal Alkynes through Divergent Gold Catalysis
An intermolecular condensation of alkynols and terminal alkynes is reported. Using IPrAuNTf(2), an efficient Au-catalyzed cyclization-alkynylation strategy furnishes (2-arylalkynyl) cyclic ethers in moderate to excellent yields (up to 94%). This strategy is extended to the synthesis of functionalize...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5313346/ https://ncbi.nlm.nih.gov/pubmed/28074975 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc09794d |
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