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Accessing Alternative Reaction Pathways of the Intermolecular Condensation between Homo-Propargyl Alcohols and Terminal Alkynes through Divergent Gold Catalysis

An intermolecular condensation of alkynols and terminal alkynes is reported. Using IPrAuNTf(2), an efficient Au-catalyzed cyclization-alkynylation strategy furnishes (2-arylalkynyl) cyclic ethers in moderate to excellent yields (up to 94%). This strategy is extended to the synthesis of functionalize...

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Bibliografski detalji
Izdano u:Chem Commun (Camb)
Glavni autori: Smith, Courtney A., Motika, Stephen E., Wojtas, Lukasz, Shi, Xiaodong
Format: Artigo
Jezik:Inglês
Izdano: 2017
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5313346/
https://ncbi.nlm.nih.gov/pubmed/28074975
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc09794d
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