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Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation of Alkynes
[Image: see text] We report the use of cationic gold complexes [Au(NHC)(CH(3)CN)][BF(4)] and [{Au(NHC)}(2)(μ–OH)][BF(4)] (NHC = N-heterocyclic carbene) as highly active catalysts in the solvent-free hydroalkoxylation of internal alkynes using primary and secondary alcohols. Using this simple protoco...
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| Publicado no: | ACS Catal |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2015
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5745073/ https://ncbi.nlm.nih.gov/pubmed/29291136 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs501976s |
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