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Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation of Alkynes

[Image: see text] We report the use of cationic gold complexes [Au(NHC)(CH(3)CN)][BF(4)] and [{Au(NHC)}(2)(μ–OH)][BF(4)] (NHC = N-heterocyclic carbene) as highly active catalysts in the solvent-free hydroalkoxylation of internal alkynes using primary and secondary alcohols. Using this simple protoco...

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Argitaratua izan da:ACS Catal
Egile Nagusiak: Veenboer, Richard M. P., Dupuy, Stéphanie, Nolan, Steven P.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: American Chemical Society 2015
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5745073/
https://ncbi.nlm.nih.gov/pubmed/29291136
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs501976s
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