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Gold-catalyzed reaction of oxabicyclic alkenes with electron-deficient terminal alkynes to produce acrylate derivatives

Oxabicyclic alkenes can react with electron-deficient terminal alkynes in the presence of a gold catalyst under mild conditions, affording the corresponding addition products in moderate yields. When using alkynyl esters as substrates, the (Z)-acrylate derivatives are obtained. Using but-3-yn-2-one...

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Autori principali: Sun, Yin-wei, Xu, Qin, Shi, Min
Natura: Artigo
Lingua:Inglês
Pubblicazione: Beilstein-Institut 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3817539/
https://ncbi.nlm.nih.gov/pubmed/24204408
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.233
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