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Reductive α-borylation of α,β-unsaturated esters using NHC–BH(3) activated by I(2) as a metal-free route to α-boryl esters
Useful α-boryl esters can be synthesized in one step from α,β-unsaturated esters using just a simple to access NHC–BH(3) (NHC = N-heterocyclic carbene) and catalytic I(2). The scope of this reductive α-borylation methodology is excellent and includes a range of alkyl, aryl substituted and cyclic and...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Chem Sci |
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| Prif Awduron: | , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
Royal Society of Chemistry
2018
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6354834/ https://ncbi.nlm.nih.gov/pubmed/30809360 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04305a |
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