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Formation of C(sp(2))—Boronate Esters by Borylative Cyclization of Alkynes Using BCl(3)

BCl(3) is an inexpensive electrophile which induces the borylative cyclization of a wide range of substituted alkynes to regioselectively form polycycles containing synthetically versatile C(sp(2))—boronate esters. It proceeds rapidly, with good yields and is compatible with a range of functional gr...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Warner, Andrew J., Lawson, James R., Fasano, Valerio, Ingleson, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY‐VCH Verlag 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4832827/
https://ncbi.nlm.nih.gov/pubmed/26237115
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505810
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