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Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters
To(M)MgHB(C(6)F(5))(3) (1, To(M) = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) catalyzes the 1,4-hydrosilylation of α,β-unsaturated esters. This magnesium hydridoborate compound is synthesized by the reaction of To(M)MgMe, PhSiH(3), and B(C(6)F(5))(3). Unlike the transient To(M)MgH formed from the...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5947512/ https://ncbi.nlm.nih.gov/pubmed/29861929 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02435h |
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