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Synthesis of (S)-3-amino-4-(difluoromethylenyl)-cyclopent-1-ene-1-carboxylic acid (OV329), a potent inactivator of γ-aminobutyric acid aminotransferase

(S)-3-amino-4-(difluoromethylenyl)cyclopent-1-ene-1-carboxylic acid (OV329, 1) is being developed for the treatment of addiction and epilepsy. The previous 14-step synthesis of OV329 was low yielding, involved an unselective α-elimination to form the cyclopentene, required the use of tert-butyllithi...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Moschitto, Matthew J., Silverman, Richard B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6262895/
https://ncbi.nlm.nih.gov/pubmed/30009604
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b01872
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