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Ta(2)(+)-mediated ammonia synthesis from N(2) and H(2) at ambient temperature

In a full catalytic cycle, bare Ta(2)(+) in the highly diluted gas phase is able to mediate the formation of ammonia in a Haber–Bosch-like process starting from N(2) and H(2) at ambient temperature. This finding is the result of extensive quantum chemical calculations supported by experiments using...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Geng, Caiyun, Li, Jilai, Weiske, Thomas, Schwarz, Helmut
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2018
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6243240/
https://ncbi.nlm.nih.gov/pubmed/30352846
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1814610115
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