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Beyond the classical thermodynamic contributions to hydrogen atom abstraction reactivity

Hydrogen atom abstraction (HAA) reactions are cornerstones of chemistry. Various (metallo)enzymes performing the HAA catalysis evolved in nature and inspired the rational development of multiple synthetic catalysts. Still, the factors determining their catalytic efficiency are not fully understood....

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Bibliografische gegevens
Gepubliceerd in:Proc Natl Acad Sci U S A
Hoofdauteurs: Bím, Daniel, Maldonado-Domínguez, Mauricio, Rulíšek, Lubomír, Srnec, Martin
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: National Academy of Sciences 2018
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6217389/
https://ncbi.nlm.nih.gov/pubmed/30254163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1806399115
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