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Beyond the classical thermodynamic contributions to hydrogen atom abstraction reactivity

Hydrogen atom abstraction (HAA) reactions are cornerstones of chemistry. Various (metallo)enzymes performing the HAA catalysis evolved in nature and inspired the rational development of multiple synthetic catalysts. Still, the factors determining their catalytic efficiency are not fully understood....

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Bibliographische Detailangaben
Veröffentlicht in:Proc Natl Acad Sci U S A
Hauptverfasser: Bím, Daniel, Maldonado-Domínguez, Mauricio, Rulíšek, Lubomír, Srnec, Martin
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2018
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6217389/
https://ncbi.nlm.nih.gov/pubmed/30254163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1806399115
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