NRVS Definition of the Facial Triad Fe(IV)=O Intermediate in Taurine Dioxygenase: Evaluation of Structural Contributions to Hydrogen Atom Abstraction

The α-ketoglutarate (αKG)-dependent oxygenases catalyze a diverse range of chemical reactions using a common high-spin Fe(IV)=O intermediate and, in most reactions, abstracts a hydrogen atom from the substrate. Previously, the Fe(IV)=O intermediate in the αKG-dependent halogenase SyrB2 was character...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:J Am Chem Soc
Hauptverfasser: Srnec, Martin, Iyer, Shyam R., Dassama, Laura M. K., Park, Kiyoung, Wong, Shaun D., Sutherlin, Kyle D., Yoda, Yoshitaka, Kobayashi, Yasuhiro, Kurokuzu, Masayuki, Saito, Makina, Seto, Makoto, Krebs, Carsten, Bollinger, J. Martin, Solomon, Edward I.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2020
Schlagworte:
Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7642179/
https://ncbi.nlm.nih.gov/pubmed/33103886
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08903
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!

Ähnliche Einträge