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NRVS Definition of the Facial Triad Fe(IV)=O Intermediate in Taurine Dioxygenase: Evaluation of Structural Contributions to Hydrogen Atom Abstraction
The α-ketoglutarate (αKG)-dependent oxygenases catalyze a diverse range of chemical reactions using a common high-spin Fe(IV)=O intermediate and, in most reactions, abstracts a hydrogen atom from the substrate. Previously, the Fe(IV)=O intermediate in the αKG-dependent halogenase SyrB2 was character...
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| הוצא לאור ב: | J Am Chem Soc |
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| Main Authors: | , , , , , , , , , , , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2020
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7642179/ https://ncbi.nlm.nih.gov/pubmed/33103886 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08903 |
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