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Site-specific incorporation of selenocysteine using an expanded genetic code and palladium-mediated chemical deprotection

Selenoproteins containing the 21(st) amino acid selenocysteine (Sec) exist in all three kingdoms of life and play essential roles in human health and development. The distinct low pKa, high reactivity and redox property of Sec also afford unique routes to protein modification and engineering. Howeve...

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Publicado en:J Am Chem Soc
Autores principales: Liu, Jun, Zheng, Feng, Cheng, Rujin, Li, Shanshan, Rozovsky, Sharon, Wang, Qian, Wang, Lei
Formato: Artigo
Lenguaje:Inglês
Publicado: 2018
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6082430/
https://ncbi.nlm.nih.gov/pubmed/29984990
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b04603
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