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Direct Access to Highly Functionalized Heterocycles through the Condensation of Cyclic Imines and α-Oxoesters

A facile, gram-scale preparation of 2-hydroxy-5,6,7,7a-tetrahydro-3H-pyrrolizin-3-ones and 2-hydroxy-6,7,8,8a-tetrahydroindolizin-3(5H)-ones from a condensation cyclization of α-oxoesters with five- and six-membered cyclic imines, respectively, is reported. This transformation enables a concise, thr...

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Detalles Bibliográficos
Publicado en:J Org Chem
Main Authors: Cusumano, Alexander Q., Boudreau, Matthew W., Pierce, Joshua G.
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6008790/
https://ncbi.nlm.nih.gov/pubmed/29206454
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b02572
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