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Additive-Free Pd-Catalyzed α-Allylation of Imine-Containing Heterocycles
[Image: see text] An additive-free Pd-catalyzed α-allylation of different imino-group-ontaining heterocycles is reported. The activation of α-CH pronucleophiles (pK(a) (DMSO) > 25) occurs without the addition of strong bases or Lewis acids using only the Pd/Xantphos catalyst system. The reaction...
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| Veröffentlicht in: | Org Lett |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical Society
2016
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5223276/ https://ncbi.nlm.nih.gov/pubmed/27936786 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b03407 |
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