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Pd-catalyzed asymmetric allylic alkylations via C–H activation of N-allyl imines with glycinates
Herein is reported the first example of palladium-catalyzed asymmetric allylic alkylation (AAA) reactions involving 2-aza-π-allyl palladium intermediates. The 2-aza-π-allyl complex was generated via a novel mode of activation of N-allyl imines. Pd-catalyzed C(sp(3))–H activation of N-allyl imines an...
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| Publicado no: | Chem Sci |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5643980/ https://ncbi.nlm.nih.gov/pubmed/29147506 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02899g |
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