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Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates

Palladium-catalyzed decarboxylative asymmetric allylic alkylation (DAAA) of allyl enol carbonates as a highly chemo-, regio- and enantio-selective process for the synthesis of ketones bearing either a quaternary or a tertiary α-stereogenic center has been investigated in detail. Chiral ligand L4 was...

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Autors principals: Trost, Barry M., Xu, Jiayi, Schmidt, Thomas
Format: Artigo
Idioma:Inglês
Publicat: 2009
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2804400/
https://ncbi.nlm.nih.gov/pubmed/19928805
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9053948
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