Palladium-Catalyzed Asymmetric Allylic Alkylation of 2-Acylimidazoles as Ester Enolate Equivalents

[Image: see text] A broad range of highly enantioenriched 2-acylimidazoles are synthesized by palladium-catalyzed decarboxylative asymmetric allylic alkylation (DAAA) of 2-imidazolo-substituted enol carbonates. The enantioenriched 2-acylimidazole products can easily be converted to the corresponding...

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Hlavní autoři: Trost, Barry M., Lehr, Konrad, Michaelis, David J., Xu, Jiayi, Buckl, Andreas K.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2908042/
https://ncbi.nlm.nih.gov/pubmed/20550121
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103771w
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