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Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates
Palladium-catalyzed decarboxylative asymmetric allylic alkylation (DAAA) of allyl enol carbonates as a highly chemo-, regio- and enantio-selective process for the synthesis of ketones bearing either a quaternary or a tertiary α-stereogenic center has been investigated in detail. Chiral ligand L4 was...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2804400/ https://ncbi.nlm.nih.gov/pubmed/19928805 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9053948 |
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