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Synthesis of (-)-Δ(9)-trans-Tetrahydrocannabinol - Stereocontrol via Mo-catalyzed Asymmetric Allylic Alkylation Reaction
[Image: see text] Δ(9)-THC is synthesized in enantiomericaly pure form, where all of the stereochemistry is derived from the molybdenum catalyzed asymmetric alkylation reaction of the extremely sterically congested bis-ortho substituted cinnamyl carbonate in high regio- and enantioselectivity.
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| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2007
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597621/ https://ncbi.nlm.nih.gov/pubmed/17266321 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol063022k |
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