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Pd-Catalyzed Enantioselective Allyl-Allyl Cross Coupling

[Image: see text] The Pd-catalyzed cross coupling of terminal allylic carbonates and allylB(pin) is described. The regioselectivity of this reaction is sensitive to the bite angle of the ligand with small bite angle ligands favoring the branched substitution product. This mode of regioselection is c...

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Autores principales: Zhang, Ping, Brozek, Laura A., Morken, James P.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2010
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2925184/
https://ncbi.nlm.nih.gov/pubmed/20681700
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105161f
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