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Enantioselective Construction of All-Carbon Quaternary Centers by Branch-Selective Pd-Catalyzed Allyl-Allyl Cross Coupling
The Pd-catalyzed cross coupling of racemic tertiary allylic carbonates and allyl boronates is described. This reaction generates all-carbon quaternary centers in a highly regioselective and enantioselective fashion. The outcome of these reactions is consistent with a process that proceeds by way of...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3131072/ https://ncbi.nlm.nih.gov/pubmed/21648464 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2039248 |
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