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The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

All-carbon quaternary stereocenters have posed significant challenges in the synthesis of complex natural products. These important structural motifs have inspired the development of broadly applicable palladium-catalyzed asymmetric allylic alkylation reactions of unstabilized non-biased enolates fo...

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Autors principals: Hong, Allen Y., Stoltz, Brian M.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4059687/
https://ncbi.nlm.nih.gov/pubmed/24944521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201201761
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