Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters

General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedded in numerous natural products have been developed. The central stereoselective transformation in our divergent strategies is the enantioselective decarboxylative alkylation of seven-membered β-ketoes...

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Main Authors: Hong, Allen Y., Bennett, Nathan B., Krout, Michael R., Jensen, Thomas, Harned, Andrew. M., Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3279929/
https://ncbi.nlm.nih.gov/pubmed/22347731
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.10.031
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