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Congested C-C Bonds by Pd-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling, A Mechanism-Guided Solution

Under the influence of a chiral bidentate diphosphine ligand, the Pd-catalyzed asymmetric cross-coupling of allylboron reagents and allylic electrophiles establishes 1,5-dienes with adjacent stereocenters in high regio- and stereoselectivity. . A mechanistic study of the coupling utilizing reaction...

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Detalhes bibliográficos
Main Authors: Ardolino, Michael J., Morken, James P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4211291/
https://ncbi.nlm.nih.gov/pubmed/24720611
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja502280w
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