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Congested C-C Bonds by Pd-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling, A Mechanism-Guided Solution
Under the influence of a chiral bidentate diphosphine ligand, the Pd-catalyzed asymmetric cross-coupling of allylboron reagents and allylic electrophiles establishes 1,5-dienes with adjacent stereocenters in high regio- and stereoselectivity. . A mechanistic study of the coupling utilizing reaction...
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| Main Authors: | , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2014
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4211291/ https://ncbi.nlm.nih.gov/pubmed/24720611 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja502280w |
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