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Electrochemical‐Induced Ring Transformation of Cyclic α‐(ortho‐Iodophenyl)‐β‐oxoesters
Cyclic α‐(ortho‐iodophenyl)‐β‐oxoesters were converted in a ring‐expanding transformation to furnish benzannulated cycloalkanone carboxylic esters. The reaction sequence started by electrochemical reduction of the iodoarene moiety. In a mechanistic rationale, the resulting carbanionic species was ad...
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| Published in: | Chemistry |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
John Wiley and Sons Inc.
2020
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7155071/ https://ncbi.nlm.nih.gov/pubmed/31850604 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905570 |
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