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Electrochemical‐Induced Ring Transformation of Cyclic α‐(ortho‐Iodophenyl)‐β‐oxoesters

Cyclic α‐(ortho‐iodophenyl)‐β‐oxoesters were converted in a ring‐expanding transformation to furnish benzannulated cycloalkanone carboxylic esters. The reaction sequence started by electrochemical reduction of the iodoarene moiety. In a mechanistic rationale, the resulting carbanionic species was ad...

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Vydáno v:Chemistry
Hlavní autoři: Strehl, Julia, Kahrs, Christoph, Müller, Thomas, Hilt, Gerhard, Christoffers, Jens
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7155071/
https://ncbi.nlm.nih.gov/pubmed/31850604
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905570
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