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Synthesis of Benzo[b]azocin‐2‐ones by Aryl Amination and Ring‐Expansion of α‐(Iodophenyl)‐β‐oxoesters

Transformation of β‐oxoesters with PhI(OCOCF(3))(2) leads to α‐(ortho‐iodophenyl)‐β‐oxoesters. These materials are the starting point for the synthesis of 6‐carboxybenzo[b]azocin‐2‐ones by a sequence of aryl amination and ring transformation. This reaction sequence starts with copper‐catalyzed forma...

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Sparad:
Bibliografiska uppgifter
I publikationen:Chemistry
Huvudupphovsmän: Dierks, Anna, Tönjes, Jan, Schmidtmann, Marc, Christoffers, Jens
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2019
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6899745/
https://ncbi.nlm.nih.gov/pubmed/31433088
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903139
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