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Systematic investigations on the reduction of 4-aryl-4-oxoesters to 1-aryl-1,4-butanediols with methanolic sodium borohydride
4-Aryl-4-oxoesters undergo facile reduction of both the keto and the ester groups with methanolic NaBH(4) at room temperature to yield the corresponding 1-aryl-1,4-butanediols whereas 4-alkyl-4-oxoesters furnish the corresponding 1,4-butanolides via selective reduction of the keto moiety. Results of...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2956461/ https://ncbi.nlm.nih.gov/pubmed/20978613 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.94 |
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