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Synthesis of Benzo[b]azocin‐2‐ones by Aryl Amination and Ring‐Expansion of α‐(Iodophenyl)‐β‐oxoesters
Transformation of β‐oxoesters with PhI(OCOCF(3))(2) leads to α‐(ortho‐iodophenyl)‐β‐oxoesters. These materials are the starting point for the synthesis of 6‐carboxybenzo[b]azocin‐2‐ones by a sequence of aryl amination and ring transformation. This reaction sequence starts with copper‐catalyzed forma...
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| 發表在: | Chemistry |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6899745/ https://ncbi.nlm.nih.gov/pubmed/31433088 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903139 |
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