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Biochemical and Structural Characterization of a Schiff Base in the Radical-Mediated Biosynthesis of 4-Demethylwyosine by TYW1

[Image: see text] TYW1 is a radical S-adenosyl-l-methionine (SAM) enzyme that catalyzes the condensation of pyruvate and N-methylguanosine to form the posttranscriptional modification, 4-demethylwyosine, in situ on transfer RNA (tRNA). Two mechanisms have been proposed for this transformation, with...

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Publicat a:J Am Chem Soc
Autors principals: Grell, Tsehai A. J., Young, Anthony P., Drennan, Catherine L., Bandarian, Vahe
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2018
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5994729/
https://ncbi.nlm.nih.gov/pubmed/29792696
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01493
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