The N-Methylpyrrolidone (NMP) Effect in Iron-Catalyzed Cross-Coupling with Simple Ferric Salts and MeMgBr

The use of N-methylpyrrolidone (NMP) as a co-solvent in ferric salt catalyzed cross-coupling reactions is crucial for achieving the highly selective, preparative scale formation of cross-coupled product in reactions utilizing alkyl Grignard reagents. Despite the critical importance of NMP, the molec...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Muñoz, Salvador B., Daifuku, Stephanie L., Sears, Jeffrey D., Baker, Tessa M., Carpenter, Stephanie H., Brennessel, William W., Neidig, Michael L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5992103/
https://ncbi.nlm.nih.gov/pubmed/29624838
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802087
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