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The Effect of β-Hydrogen Atoms on Iron Speciation in Cross-Couplings with Simple Iron Salts and Alkyl Grignard Reagents

The elucidation of the effects of β-hydrogen containing alkyl Grignard reagents in simple ferric salt cross-coupling is presented. The reaction of FeCl(3) with EtMgBr in THF leads to the formation of the cluster species [Fe(8)Et(12)](2−), a rare example of a structurally characterized metal complex...

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Detaylı Bibliyografya
Yayımlandı:Angew Chem Int Ed Engl
Asıl Yazarlar: Sears, Jeffrey D., Muñoz, Salvador B., Daifuku, Stephanie L., Shaps, Ari A., Carpenter, Stephanie H., Brennessel, William W., Neidig*, Michael L.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2019
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6472485/
https://ncbi.nlm.nih.gov/pubmed/30653812
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813578
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