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The Effect of β-Hydrogen Atoms on Iron Speciation in Cross-Couplings with Simple Iron Salts and Alkyl Grignard Reagents
The elucidation of the effects of β-hydrogen containing alkyl Grignard reagents in simple ferric salt cross-coupling is presented. The reaction of FeCl(3) with EtMgBr in THF leads to the formation of the cluster species [Fe(8)Et(12)](2−), a rare example of a structurally characterized metal complex...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6472485/ https://ncbi.nlm.nih.gov/pubmed/30653812 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813578 |
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