Isolation, Characterization, and Reactivity of Fe(8)Me(12)(−): Kochi’s S = 1/2 Species in Iron-Catalyzed Cross-Couplings with MeMgBr and Ferric Salts

Iron-catalyzed cross-couplings with simple ferric salts have been known since the 1970s, pioneered by Kochi for cross-coupling using alkylmagnesium nucleophiles including MeMgBr. While Kochi observed the formation of a S = 1/2 iron species in reactions of simple ferric salts with MeMgBr proposed to...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Muñoz, Salvador B., Daifuku, Stephanie L., Brennessel, William W., Neidig, Michael L.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5032139/
https://ncbi.nlm.nih.gov/pubmed/27227322
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03760
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