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Isolation and Characterization of a Tetramethyliron(III) Ferrate: An Intermediate in the Reduction Pathway of Ferric Salts with MeMgBr

[Image: see text] While iron-catalyzed Kumada cross-coupling reactions with simple iron salts have been known since the early 1970s, the nature of the in situ-formed iron species remains elusive. Herein, we report the synthesis of the homoleptic tetralkyliron(III) ferrate complex [MgCl(THF)(5)][FeMe...

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Publicat a:J Am Chem Soc
Autors principals: Al-Afyouni, Malik H., Fillman, Kathlyn L., Brennessel, William W., Neidig, Michael L.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4227835/
https://ncbi.nlm.nih.gov/pubmed/25333789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5080757
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