Cargando...
Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols
Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated “spin-center shift” (SCS) mechanism. Alcohols, however, remain underused as alkylating agents in synthetic chemistry due to their low reactiv...
Gardado en:
| Publicado en: | J Am Chem Soc |
|---|---|
| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2018
|
| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5896313/ https://ncbi.nlm.nih.gov/pubmed/29400958 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b12768 |
| Tags: |
Engadir etiqueta
Sen Etiquetas, Sexa o primeiro en etiquetar este rexistro!
|