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A “seleno-effect” differentiates the roles of redox active cysteine residues in Plasmodium falciparum thioredoxin reductase()
Here, we introduce the concept of the “seleno effect” in the study of oxidoreductases that catalyze thiol/disulfide exchange reactions. In these reactions, selenium can replace sulfur as a nucleophile, electrophile, or leaving group, and the resulting change in rate (the seleno effect) is defined as...
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| Publicado no: | Biochemistry |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5866731/ https://ncbi.nlm.nih.gov/pubmed/29485860 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.8b00004 |
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