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Pd-Catalyzed Acyl C–O Bond Activation for Selective Ring-opening of α-Methylene-β-lactones with Amines
A Pd-catalyzed ring-opening of β-lactones with various types of amines (primary, secondary and aryl) to provide β-hydroxy amides with excellent selectivity towards acyl C–O bond cleavage is reported. The utility of this protocol is demonstrated in an asymmetric kinetic resolution providing enantioen...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5839468/ https://ncbi.nlm.nih.gov/pubmed/28375015 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00494 |
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