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The α-tertiary amine motif drives remarkable selectivity for Pd-catalyzed carbonylation of β-methylene C–H bonds
The selective C–H carbonylation of methylene bonds in the presence of traditionally more reactive methyl C–H and C(sp(2))–H bonds in α-tertiary amines is reported. The exceptional selectivity is driven by the bulky α-tertiary amine motif, which we hypothesise orientates the activating C–H bond proxi...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5855970/ https://ncbi.nlm.nih.gov/pubmed/29568467 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03876c |
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