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Pd(II)-catalyzed Enantioselective Methylene C(sp(3))–H Bond Activation
The development of catalytic enantioselective C(sp(3))–H metal insertion reactions has been a significant challenge. Moderate success has recently been achieved via Pd-catalyzed desymmetrization of prochiral C–H bonds located on two different carbon centers. Herein, we report the discovery of chiral...
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| Udgivet i: | Science |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5516954/ https://ncbi.nlm.nih.gov/pubmed/27701111 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaf4434 |
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