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Pd(II)-catalyzed Enantioselective Methylene C(sp(3))–H Bond Activation

The development of catalytic enantioselective C(sp(3))–H metal insertion reactions has been a significant challenge. Moderate success has recently been achieved via Pd-catalyzed desymmetrization of prochiral C–H bonds located on two different carbon centers. Herein, we report the discovery of chiral...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Science
Prif Awduron: Chen, Gang, Gong, Wei, Zhuang, Zhe, Andrä, Michal S., Chen, Yan-Qiao, Liu, Tao, Yu, Jin-Quan
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2016
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5516954/
https://ncbi.nlm.nih.gov/pubmed/27701111
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaf4434
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