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Reactivity of uranium(iii) with H(2)E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes

We report the syntheses, electronic properties, and molecular structures of a series of mono- and dinuclear uranium(iv) hydrochalcogenido complexes supported by the sterically demanding but very flexible, single N-anchored tris(aryloxide) ligand ((Ad)ArO)(3)N)(3–). The mononuclear complexes [(((Ad)A...

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Pubblicato in:Chem Sci
Autori principali: Franke, Sebastian M., Rosenzweig, Michael W., Heinemann, Frank W., Meyer, Karsten
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5811169/
https://ncbi.nlm.nih.gov/pubmed/29560170
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02602k
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