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Uranium(iv) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond

Herein, we report the synthesis and characterization of a series of terminal uranium(iv) hydrosulfido and sulfido complexes, supported by the hexadentate, tacn-based ligand framework ((Ad,Me)ArO)(3)tacn(3–) (= trianion of 1,4,7-tris(3-(1-adamantyl)-5-methyl-2-hydroxybenzyl)-1,4,7-triazacyclononane)....

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Publicado en:Chem Sci
Main Authors: Rosenzweig, Michael W., Scheurer, Andreas, Lamsfus, Carlos A., Heinemann, Frank W., Maron, Laurent, Andrez, Julie, Mazzanti, Marinella, Meyer, Karsten
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6024247/
https://ncbi.nlm.nih.gov/pubmed/30034726
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00677a
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