Synthesis and reactivity of a terminal uranium(iv) sulfide supported by siloxide ligands

The reactions of the tetrasiloxide U(iii) complexes [U(OSi(O(t)Bu)(3))(4)K] and [U(OSi(O(t)Bu)(3))(4)][K18c6] with 0.5 equiv. of triphenylphosphine sulfide led to reductive S-transfer reactions, affording the U(iv) sulfide complexes [SU(OSi(O(t)Bu)(3))(4)K(2)](2), 1, and [{SU(OSi(O(t)Bu)(3))(4)K(2)}...

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Detalles Bibliográficos
Publicado en:Chem Sci
Main Authors: Andrez, Julie, Pécaut, Jacques, Scopelliti, Rosario, Kefalidis, Christos E., Maron, Laurent, Rosenzweig, Michael W., Meyer, Karsten, Mazzanti, Marinella
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6024242/
https://ncbi.nlm.nih.gov/pubmed/30034725
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00675b
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