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Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U[double bond, length as m-dash]N[double bond, length as m-dash]U bonding imposed by the supporting ligand. The U(4+)–U(4+) nitride complexes, [NBu(4)][{(((t)BuO)(3)SiO)(3)U}(2)(μ-N)], [N...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Palumbo, Chad T., Barluzzi, Luciano, Scopelliti, Rosario, Zivkovic, Ivica, Fabrizio, Alberto, Corminboeuf, Clémence, Mazzanti, Marinella
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6853081/
https://ncbi.nlm.nih.gov/pubmed/31803458
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02149c
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