Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(iv) complexes

High-valent iron(iv)-oxo species are key intermediates in the catalytic cycles of a range of O(2)-activating iron enzymes. This work presents a detailed study of the electronic structures of mononuclear ([Fe(IV)(O)(L)(NCMe)](2+), 1, L = tris(3,5-dimethyl-4-methoxylpyridyl-2-methyl)amine) and dinucle...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: Ye, Shengfa, Xue, Genqiang, Krivokapic, Itana, Petrenko, Taras, Bill, Eckhard, Que Jr, Lawrence, Neese, Frank
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Royal Society of Chemistry 2015
Gaiak:
Chemistry
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4583211/
https://ncbi.nlm.nih.gov/pubmed/26417426
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03268c
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